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Archive International Journal of Materials Research - Issue 2012/04 Back to overview
New pressure induced phase transitions in mullite-type Bi2(Fe4–xMnx)O10–d complex oxides
Single phased mullite-type Bi2Fe4–xMnxO10–δmixed crystals (0.25 ≤ x ≤ 3.125) and the end-member Bi2Fe4O9, synthesized from the oxides by reaction sintering up to 825 °C, were studied at high-pressures in order to probe their high-pressure behavior and any possible structural phase transitions. In-situ synchrotron radiation-based powder X-ray diffraction was carried out in a diamond anvil cell, under quasi-hydrostatic conditions, up to a pressure of about 20 GPa at room temperature for each sample. A pressure-induced phase transition was found in all samples. The transition appeared spread over a pressure range and was not completed at the top investigated pressure. This is the first report of a pressure-induced phase transition in Bi2Fe4–xMnxO10–δmixed crystals.

From Patricia E. Kalita 1 | Andrew L. Cornelius 1 | Kristina E. Lipinska 2 | Michael W. Lufaso 3 | Zachary R. Kann 3 | Stanislav Sinogeikin 4 | Oliver A. Hemmers 2 | Hartmut Schneider 5
1High Pressure Science & Engineering Center, Dept. of Physics, University of Nevada Las Vegas, NV, USA
2Harry Reid Center for Environmental Studies, University of Nevada Las Vegas, NV, USA
3Department of Chemistry, University of North Florida, Jacksonville, FL, USA
4Geophysical Laboratory, Carnegie Institution of Washington, Washington, DC, USA
5Institute of Crystallography, University of Köln, Köln, Germany
(Received 01.12.2011; accepted 26.01.2012)
Appeared in International Journal of Materials Research 2012/04, Page 464-468
DOI: 10.3139/146.110719
Direct link: http://www.ijmr.de/MK110719
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